(146.)

Coal, the combustible almost universally used in steam-engines, is a substance, the principal constituents of which are carbon and hydrogen, occasionally mixed with sulphur in a small proportion, and earthy incombustible matter. In different sorts of coal the proportions of these constituents vary, but in coal of good quality about three quarters of the whole weight of the combustible is carbon.

When carbon is heated to a temperature of about 700° in an atmosphere of pure oxygen, it will combine chemically with that gas, and the product will be the gas called carbonic acid. The volume of carbonic acid produced by this combination, will be exactly equal to that of the oxygen combined with the carbon, and therefore the weight of a given volume of the gas will be increased by the weight of carbon which enters the combination. It is found that two parts by weight of oxygen combined with three of carbon, form carbonic acid. The weight of the carbonic acid, therefore, produced in the combustion, will be greater than the weight of the oxygen, bulk for bulk, in the proportion of five to two, the volume being the same and the gases being [Pg253] compared at the same temperatures and under equal pressures. In this combination heat is evolved in very large quantities. This effect arises from the heat previously latent in the carbon and oxygen being rendered sensible in the process of combustion. The carbonic acid proceeding from the combustion is by such means raised to a very high temperature, and the carbon during the process acquires a heat so intense as to become luminous; no flame, however, is produced.

Hydrogen, heated to a temperature of about 1000°, in contact with oxygen will combine with the latter, and a great evolution of heat will attend the process; the gases will be rendered luminous, and flame will be produced. The product of this process will be water, which being exposed to the intense heat of combustion, will be immediately converted into steam. Hydrogen combines with eight times its own weight of oxygen, producing nine times its own weight of water.

Hydrogen gas is, however, not usually disengaged from coal in a simple form, but combined chemically with a certain portion of carbon, the combination being called carburetted hydrogen. Pure hydrogen burns with a very faintly luminous blue flame, but carburetted hydrogen gives that bright flame occasionally having an orange or reddish tinge, which is seen to issue from burning coals: this is the gas used for illumination, being expelled from the coal by the process of coking, and conducted to the various burners through proper pipes.

The sulphur, which in a very small proportion is contained in coals, is also combustible, and combines in the process of combustion with oxygen, forming sulphurous acid: it is also sometimes evolved in combination with hydrogen, forming sulphuretted hydrogen.

Atmospheric air consists of two gases, azote and oxygen, mixed together in the proportion of four to one; five cubic feet of atmospheric air consisting of four cubic feet of azote and one of oxygen. Any combustible will combine with the oxygen contained in atmospheric air, if raised to a temperature somewhat higher than that which is necessary to cause its combustion in an atmosphere of pure oxygen.

If coals, therefore, or other fuel exposed to atmospheric [Pg254] air, be raised to a sufficiently high temperature, their combustible constituents will combine with the oxygen of the atmospheric air, and all the phenomena of combustion will ensue. In order, however, that the combustion should be continued, and should be carried on with quickness and activity, it is necessary that the carbonic acid, and other products, should be removed from the combustible as they are produced, and fresh portions of atmospheric air brought into contact with it; otherwise the combustible would soon be surrounded by an atmosphere composed chiefly of carbonic acid to the exclusion of atmospheric air, and therefore of uncombined oxygen, and consequently the combustion would cease, and the fuel be extinguished. To maintain the combustion, therefore, a current of atmospheric air must be constantly carried through the fuel: the quantity and force of this current must depend on the quantity and quality of the fuel to be consumed. It must be such that it shall supply sufficient oxygen to the fuel to maintain the combustion, and not more than sufficient, since any excess would be attended with the effect of absorbing the heat of combustion, without contributing to the maintenance of that effect.

Heat is communicated from body to body in two ways, by radiation and by contact.

Rays of heat issue from a heated body, and are dispersed through the surrounding space in a manner, and according to laws, similar to those which govern the radiation of light. The heat thus radiated meeting other bodies is imparted to them, and penetrates them with more or less facility according to their physical qualities.

A heated body also brought into contact with another body of lower temperature, communicates heat to that other body, and will continue to do so until the temperature of the two bodies in contact shall be equalised. Heat proceeds from fuel in a state of combustion in both these ways: the heated fuel radiates heat in all directions around it, and the heat thus radiated will be imparted to all parts of the furnace which are exposed to the fuel.

The gases, which are the products of the combustion, escape from the fuel at a very high temperature, and consequently, in acquiring that temperature they absorb a considerable [Pg255] quantity of the heat of combustion. But besides the gases actually formed in the process of combustion, the azote forming four fifths of the air carried through the fuel to support the combustion, absorbs heat from the combustible, and rises into the upper part of the furnace at a high temperature. These various gases, if conducted directly to the chimney, would carry off with them a considerable quantity of the heat. Provision should therefore be made to keep them in contact with the boiler such a length of time as will enable them to impart such a portion of the heat which they have absorbed from the fuel, as will still leave them at a temperature sufficient, and not more than sufficient, to produce the necessary draft in the chimney.